Honestly, if you have never used containers before I would suggest starting with docker as it has more readily accessible beginner walk through and tutorials. From there, you will have a good idea as to switching to podman is the right move for you or not.
Personally, I started with docker and haven’t moved from there since I don’t see a need (yet). I have dozens of services running on docker. I don’t know how heavy of a lift it would be to learn podman but like I said, I don’t feel the need to do so.
Maybe try out both and see which one you like more?